If you're looking for freeware buring applications then check out IMGBurn. You can download it from:
http://www.imgburn.com/index.php?act=download
Here's a guide on how to burn DVDs with IMGBurn:
http://forum.imgburn.com/index.php?showtopic=4632
I've never actually used this application before, but I've heard good things about it. The guide is really detailed so you shouldn't have any problems burning a disc.
A lot of people on this board also recommend a burning application called "Ones". You can download it from:
http://www.afterdawn.com/software/cd...rassi_ones.cfm
It's not freeware.
I personally used Nero Burning ROM (version 6)
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