Actually it's very easy to find out if it's PAL or NTSC.
PAL resolution: 720*576, 704*576
NTSC resolution: 720*480
Also the framerate is different. PAL has got 25fps, NTSC has got 29.97fps. And there are software that can show you a lot of details including the format. I use MediaInfo which is indeed easy and realiable helper
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